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      N-甲基二乙醇胺中的陰離子分析

      更新時間:2010-10-20  點擊次數:3078

      N-甲基二乙醇胺陰離子報告

      Printing time: Wed Sep 29 12:40:04 2010

      Injection time: Wed Sep 29 11:37:55 2010

      operator: (temporary), system administrator

      分析條件:  :cic-200     流速:1.0ml/min     量程:1

                分離柱:sh-ac      流動相: 碳酸鈉    檢測方式抑制電導

      數據僅供參考,不做判定依據,采用外標法單點校正。

      標準品譜圖:

      ------------------------------------------------

      Rank   Time     Name     Quantity   Area        

      ------------------------------------------------

      1      4.475    COOH     2          1135007     

      2      5.268    CL       2          2095252     

      3      7.928    NO3      2          1022979     

      4      13.107   H2PO4    5          1239713     

      5      15.043   SO4      3          1908172     

      6      16.782   OXALIC   2          10855890    

      7      21.006   S2O3     2          13394106    

      ------------------------------------------------

      Total                    18         31651119    

      1#樣品譜圖:

      樣品稀釋2500倍過0.22微米濾膜,進樣計算。

      File opened: E:\\ÕŽõ÷\\2010\\¶þÒÒ´¼°·\\1# 2500 (20100929 11;37;55).hw

      ------------------------------------------------

      Rank   Time     Name     Quantity   Area        

      ------------------------------------------------

      1      4.382    COOH     0          0           

      2      5.438    CL       36.21      15863       

      3      7.724    NO3      0          0           

      4      13.488   H2PO4    1.167e+004 1157335     

      5      14.568   SO4      0          0           

      6      16.401   oxalic   0          0           

      7      20.362   s2o3     0          0           

      ------------------------------------------------

      Total                    1.171e+004 1173198     

      3#樣品譜圖:

      樣品稀釋1000倍過0.22微米濾膜,進樣計算

      ------------------------------------------------

      Rank   Time     Name     Quantity   Area        

      ------------------------------------------------

      1      4.604    COOH     86.3       48973       

      2      5.442    CL       135.6      142021      

      3      7.982    NO3      0          0           

      4      13.545   H2PO4    2913       722205      

      5      15.523   SO4      207.4      131902      

      6      17.407   OXALIC   8.695      47199       

      7      21.831   S2O3     22.7       152014      

      ------------------------------------------------

      Total                    3374       1244314     

      5#樣品譜圖:(樹脂處理)

      樣品稀釋50倍,過陽離子交換樹脂,過0.22微米濾膜,進樣計算

      ------------------------------------------------

      Rank   Time     Name     Quantity   Area        

      ------------------------------------------------

      1      4.517    COOH     20.49      232579      

      2      5.323    CL       7.445      155995      

      3      7.982    NO3      0.9533     9752        

      4      13.287   H2PO4    3.711      18401       

      5      15.203   SO4      4.314      54877       

      6      0.000    OXALIC   0          0           

      7      0.000    S2O3     0          0           

      ------------------------------------------------

      Total                    36.91      471604      

      5#樣品譜圖:

      樣品稀釋50倍,過0.22微米濾膜,進樣計算

      ------------------------------------------------

      Rank   Time     Name     Quantity   Area        

      ------------------------------------------------

      1      4.563    COOH     23.46      266259      

      2      5.365    CL       1.575      33005       

      3      7.982    NO3      0          0           

      4      13.381   H2PO4    2.479      12293       

      5      15.356   SO4      1.63       20731       

      6      17.407   OXALIC   0          0           

      7      21.831   S2O3     0          0           

      ------------------------------------------------

      Total                    29.14      332288      

      2#樣品譜圖:(稀釋10倍)

      樣品稀釋10倍,過0.22微米濾膜,進樣計算

      ------------------------------------------------

      Rank   Time     Name     Quantity   Area        

      ------------------------------------------------

      2      4.419    COOH     6.608      3283        

      3      5.173    CL       640.7      701710      

      6      7.785    NO3      未計算          99010       

      7      12.916   H2PO4    未計算          3021572     

      8      14.780   SO4      212.8      240990      

      9      16.492   oxalic   6.543      35937       

      10     20.362   s2o3     0          0           

      ------------------------------------------------

      Total                    866.7      4102502     

      4#樣品譜圖:(稀釋10倍)

      樣品稀釋10倍,過0.22微米濾膜,進樣計算

      ------------------------------------------------

      Rank   Time     Name     Area%      Area        

      ------------------------------------------------

      1      4.370    COOH     632.2      46206       

      2      5.172    CL       1.523e+004 1113462     

      3      7.787    NO3      1219       89098       

      4      12.897   H2PO4    2.35e+004  1716794     

      5      14.791   SO4      7025       513479      

      6      16.503   oxalic   1457       106517      

      7      20.769   s2o3     939.7      68681       

      ------------------------------------------------

      Total                    50003      3654237     

      6#樣品譜圖:(稀釋10倍)

      ------------------------------------------------

      Rank   Time     Name     Area%      Area        

      ------------------------------------------------

      1      4.418    COOH     0.09465    1593        

      2      5.178    CL       68.65      1155244     

      3      7.803    NO3      5.423      91276       

      4      12.861   H2PO4    9.984      168035      

      5      14.774   SO4      15.17      255255      

      6      16.559   oxalic   0.683      11495       

      ------------------------------------------------

      Total                    100        1682898     

      1#樣品磷酸二氫根加標

      ----------------------------------------------

      Rank   Time     Name    Area%      Area        

      ----------------------------------------------

      1     13.568   H2PO4   41.58      9680883     

      2     15.421   SO4     1.885      438757      

      ----------------------------------------------

      Total                   100        23279894    

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